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History and Working of Batteries

 
     
 

 

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The Functioning of Batteries
 

Batteries are something we use day in and day out. They make the seemingly impossible possible; they make appliances run without being connected to a power socket. It is like carrying electricity around in your pocket. The only catch here is that the device you want to use needs to be adaptable for battery usage. A battery is basically an electric cell that converts chemical energy into electricity. Some of the types of a battery that we can't do without today include laptop battery, cell phone battery, automotive battery etc.

The earliest documentation regarding electrochemical batteries dates back to 1800. Telegraph systems were using batteries in the 1830s and by the 1870s batteries had found widespread usage. The 1900s saw the usage of flashlights. The use of domestic radio receivers caught on in the 1920s.

An inner view
A battery may be single celled or may consist of two of more cells connected in a series. The main components of a battery are: an electrolyte that may be either liquid, paste-like or solid; a positive electrode and a negative electrode. The electrodes produce ions and the electrolyte is the medium that conducts the ions. When a battery is connected to a device that needs to be powered, electricity starts flowing. The battery on/off switches in a battery-powered device are used for this purpose. 

Types of batteries
Batteries can be classified as primary, those that cannot be easily recharged, and secondary batteries that can be recharged and reused several times over. Zinc-carbon, alkaline, and lithium batteries are examples of primary batteries. Examples of rechargeable and reusable batteries are lead-acid car batteries and nickel-cadmium batteries for small electronics. 

You may have observed the +ve and -ve signs while inserting batteries into appliances. These are the two terminals and the electrons produced in a battery gather at the negative terminal. They then flow through the appliance to which the battery is connected, make the appliance work and flow back into the battery through the positive terminal. Once they re-enter the battery, more chemical reactions take place and more electrons are produced and as a result the cycle keeps on repeating itself till the appliance is turned off.

Let's take a closer look at the two types of cells.

The Leclanché cell
The most common form of primary cell used is the Leclanché cell. The French chemist Georges Leclanché invented this type of cell in the 1860s. The popular name for this type of cell is a dry cell or flashlight battery. The Leclanché cell used nowadays is surprisingly similar to its original version. The electrolyte in this cell is a mixture of ammonium chloride and zinc chloride in a paste like form.


The negative electrode and the outside shell of the cell are made of zinc. The positive electrode is in the form of a carbon rod and is surrounded by a mixture of carbon and manganese dioxide. The amount of electricity produced by a Leclanché cell is about 1.5 V.
 

Leclanché Cell
The Leclanche cell

The storage battery
A widely used lead acid battery, the storage battery was invented in 1859 by the French physicist Gaston Planté. Reversing the chemical reaction can recharge this battery. It consists of three or six cells, which are connected in a series. So the electricity generated by it is very strong.

Because of this, it has  found wide usage in automobiles, trucks and other vehicles. The catch here is that this type of battery runs down very quickly. However its ability to recharge itself while in operation has removed the hurdle and is the main reason for its widespread usage.  

During recharging the chemical reactions that take place when the battery is discharging current are reversed and the original chemical balance is restored. This being a continuous process, the battery can work for a long time without interruption. The electrolyte in this battery is a dilute solution of sulphuric acid, the negative electrode is made of lead, and the positive electrode is made of lead dioxide. 

Storage Battery
A fully charged lead storage cell

 

 

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